A parametric study on syngas production by adding CO2 and CH4 on steam gasification of biomass system using ASPEN Plus

Abstract Biomass gasification technology is increasingly employed as an environmentally friendly energy source, primarily due to its minimal impact on the environment and its ability to mitigate pollution. This technology excels in producing gas with exceptionally high hydrogen content, making it a valuable source for both fuel and energy carriers. Hydrogen (H 2 ), renowned for its stability and lack of detrimental environmental effects, holds great significance in various applications related to energy utilization and sustainability. In the current work, wood sawdust was utilized as the biomass feedstock for syngas production. The research focused on examining the impact of introducing carbon dioxide (CO 2 ) and methane (CH 4 ) gases into the Gibbs reactors. The steam gasification process was modeled by the ASPEN Plus software, allowing for comprehensive analysis and simulation of the gasification reactions. According to the obtained results, the modeling performed in this study demonstrates good predictive capability when compared to the experimental data. It was shown that when the ratio of CO 2 to biomass (C/B) increases, the MFR (mass flow rates) of H 2 as well as CH 4 decrease, whereas the flow rates of CO 2 and carbon monoxide (CO) increase. These findings indicate the influence of the C/B ratio on the distribution of different gases within the gasification process. The reduction in MFR of hydrogen when transitioning from C/B = 0 to C/B = 1 in modes a and b is quantified as 17.51 % and 16.39 %, respectively. These percentages represent the magnitude of the decrease in hydrogen MFR for each specific mode when comparing two carbon dioxide to biomass ratios. When the CH 4 to biomass (M/B) ratio increases, the mass flow rates of H 2 exhibit a consistent upward trend, while the MFR of CO 2 displays a descending form. Specifically, when in the Gibbs reactor, M/B rises from 0 to 1 for modes a and b, the mass flow rates of H 2 experience significant increases of 265 % and 243 %, respectively. These findings underscore the direct relationship between the M/B ratio and hydrogen production, highlighting the potential for enhanced hydrogen yields with higher M/B ratios in the studied modes.