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Abstract We have synthesized a quinone‐incorporated bistriarylamine donor‐acceptor‐donor (D–A–D) semiconductor 1 by B(C 6 F 5 ) 3 (BCF) catalyzed C−H/C−H cross coupling via radical ion pair intermediates. Coordination of Lewis acids BCF and Al(OR F ) 3 (R F =C(CF 3 ) 3 ) to the semiconductor 1 afforded diradical zwitterions 2 and 3 by integer electron transfer. Upon binding to Lewis acids, the LUMO energy of 1 is significantly lowered and the band gap of the semiconductor is significantly narrowed from 1.93 eV ( 1 ) to 1.01 eV ( 2 ) and 1.06 eV ( 3 ). 2 and 3 are rare near‐infrared (NIR) diradical dyes with broad absorption both centered around 1500 nm. By introducing a photo BCF generator, 2 can be generated by light‐dependent control. Furthermore, the integer electron transfer process can also be reversibly regulated via the addition of CH 3 CN. In addition, the temperature of 2 sharply increased and reached as high as 110 °C in 10 s upon the irradiation of near‐infrared‐II (NIR‐II) laser (1064 nm, 0.7 W cm −2 ), exhibiting a fast response to laser. It displays excellent photothermal stability with a photothermal (PT) conversion efficiency of 62.26 % and high‐quality PT imaging.
Kong et al. (Tue,) studied this question.