Photoredox-catalysed arylamination of non-anomeric exoglycals with aryl sulfinamides via radical Smiles rearrangement

Key Points

• The aim is to explore non-anomeric exoglycals as effective substrates in photoredox-catalysed reactions.
• Utilized photoredox conditions to facilitate arylamination.
• Focused on non-anomeric exoglycals and aryl sulfinamides.
• Reactions were analyzed for efficiency and product formation.
• Photoredox conditions enabled successful arylamination of exoglycals.
• Demonstrated notable yields compared to traditional methods.
• Radical Smiles rearrangement showed promise for new glycosylation strategies.