We present an asymptotic approach toward the standard Landau–Zener problem based on two linearly independent elementary waves of constant amplitude but time-dependent phase. The two contributions to this phase are quadratic and logarithmic in time and result from the linear chirp of the energies and the lowest order correction in the coupling between the two levels in the long-time limit. Indeed, our solutions, subjected to initial conditions at a large but finite time in the past, are valid for large negative and large positive times. Due to their asymptotic nature, they are not valid in the neighborhood of the moment when the levels cross. However, as the starting point of the dynamics moves further into the past, the time interval of the break-down of our asymptotic solutions shrinks and vanishes in the limit of the infinite past, which corresponds to the standard Landau–Zener situation. Our approach explains not only every feature of the exact solution but yields deeper insight into the origin of the effects. In particular, it (i) brings to light the subtleties involved in the asymptotic limit leading to the standard expressions for the Landau–Zener transition amplitudes, (ii) identifies the logarithmic phase as the origin of the exponential transition probability amplitude, and (iii) reveals the structure of the lowest order corrections to the Landau–Zener result when the starting point is not in the infinite past.
Glasbrenner et al. (Sun,) studied this question.