A postpolymerization N-alkylamide functionalization strategy was employed to develop vinyl-addition polynorbornene (VA-PNB) derivatives capable of interchain hydrogen-bonding interactions. Vinyl-addition poly(5-methyl-2-norbornene-gradient-methyl 5-norbornene-2-carboxylate)s (VA-P(MeNB-grad-NBE)s) with varying methyl ester contents were synthesized using a catalyst system of Pd2(dba)3/PCy3/Ph3C+B(C6F5)4−. These copolymers reacted with various alkylamines under the catalysis of 1,5,7-triazabicyclo4.4.0dec-5-ene, affording vinyl-addition poly5-methyl-2-norbornene-gradient-(methyl 5-norbornene-2-carboxylate-random-N-alkyl 5-norbornene-2-carboxamide)s (VA-PMeNB-grad-(NBE-r-NBRA)s; R = H (hexyl), O (octyl), D (decyl), DD (dodecyl)). These terpolymers, along with a homopolymer (VA-PMeNB) and precursor copolymers, were subjected to a comparative analysis of their physical properties to elucidate the effects of N-alkylamide functionalization. Notably, introducing only 10 mol % N-dodecylamide side chains effectively improved both tensile strength and toughness, while resulting in only a minor decrease in the glass transition temperature. The successful formation of an adaptable network is achieved by low steric congestion and the dynamic hydrogen-bonding behavior of the N-alkylamide side chains, both of which are controlled by their content and length.
Park et al. (2026) studied this question.
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