The dynamic self-assembly and phase separation of donor–acceptor blends are processes that dictate the nanoscale morphology in organic solar cells. Here, we employ a fluidics-inspired framework, integrating dissipative particle dynamics simulations with percolation theory, to investigate the morphogenesis of two non-fullerene systems: P3HT-PPerAcr and P3HT-PFTBT. We analyze monomeric and homopolymer blends, and copolymer macrostructures, focusing on how key parameters such as temperature and polymer chain flexibility govern the dynamic evolution towards percolating networks. Our simulations captured the fundamental fluidic behavior and universal scaling near the critical percolation threshold (χc). The critical exponent β revealed distinct universality classes dictated by system compatibility and flexibility: monomeric and flexible homopolymer blends below the critical temperature (Tc) exhibit mean field behavior (β ≈ 1). In contrast, monomeric systems above χc and flexible copolymers below χc display 3D percolation behavior (β ≈ 0.45). In the case of flexible copolymeric macromolecules, above percolation threshold a quasi-bidimensional behavior emerge with (β ≈ 0.1). Notably, semi-rigid and rigid homopolymeric and copolymeric linear architectures induce a dimensional crossover, yielding quasi-2D (β ≈ 0.14) and quasi-1D (β ≈ 0.0) morphologies. These findings establish a direct link between tunable fluidic interactions, chain dynamics, and the emergence of optimal bicontinuous percolation networks.
Mayoral-Villa et al. (Wed,) studied this question.