Colloidal quantum dots are attractive for short-wave infrared photodetectors owing to their solution processability and tunable bandgaps. However, excessive dark current remains an issue for low bandgap absorbers, where generation-recombination and tunneling currents become prominent. Diode architectures for photocarrier extraction rely on strong internal electric fields, which can amplify these leakage pathways. Here, we introduce a field-tailoring strategy to reshape the internal field distribution and suppress leakage currents. Using an indium arsenide absorber and a wide-bandgap p-type indium arsenide hole transport layer, we modulate the doping density via carbazole-based phosphonic acid ligands, enabling tuning of the internal field and band alignment. The device exhibits a dark current of 9.7 × 10⁻⁴ mA cm⁻² at −0.2 V, with a response time of 24 ns and a detectivity of 5 × 10¹¹ Jones at 1500 nm. The approach is extended to inverted architecture, demonstrating low-noise, high-speed photodetection beyond 1500 nm. Park et al. report a field-tailoring strategy by using n-type InAs as the absorber and p-type InAs as the hole transport layer to suppress leakage current for colloidal quantum dot photodetectors, enabling a low dark current of 9.7E-7 A cm2 and fast response time of 24 ns at 1,500 nm.
Park et al. (Thu,) studied this question.