What question did this study set out to answer?

To evaluate the effectiveness of a chiral Mn(II) catalyst for highly enantioselective oxidation reactions.

April 10, 2026

Highly Enantioselective Oxidation Reactions Using a Tetradentate Mn(II) Catalyst Based on ( S , S )-1,2-Diaminocyclohexane

Key Points

To evaluate the effectiveness of a chiral Mn(II) catalyst for highly enantioselective oxidation reactions.
Application of a chiral Mn(II) catalyst derived from trans-1,2-diaminocyclohexane.
Oxidation of mono-, di-, and trisubstituted olefins.
Oxidation of various organosulfur(II) compounds.
Achieved high enantioselectivity in oxidation reactions.
Successfully oxidized a range of olefins and organosulfur compounds.

Abstract

Described herein is the application of a chiral Mn(II) catalyst (6) derived from the commercially available chiral diamine trans-1,2-diaminocyclohexane to the highly enantioselective oxidation of a variety of mono-, di-, and trisubstituted olefins or various organosulfur(II) compounds.

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Highly Enantioselective Oxidation Reactions Using a Tetradentate Mn(II) Catalyst Based on ( S , S )-1,2-Diaminocyclohexane

Key Points

Abstract

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