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In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and NH2BH25. A metal borohydride complex has been isolated as a dormant form of the catalyst which can be reactivated by reaction with H2.
Denney et al. (Thu,) studied this question.
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