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Within the broader area of heterobimetallic catalysis, Al/M compounds (M = any metal) are promising for the design and execution of catalytic manifolds. This Perspective reviews recent advances in Al/M heterobimetallic catalysis, focusing on their catalytic applications. Topics include polymerization, epoxide activation and carbonylation, C–H functionalization, and other important catalytic transformations mediated by Al/M catalysts. In each case, the mechanistic role of the aluminum site is highlighted. A broad range of Al-containing metalloligands and Al/M combinations is included to construct this comprehensive perspective.
Singh et al. (Mon,) studied this question.
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