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A three dimensional -NH(2) functionalized Zeolitic Tetrazolate Framework (ZTF-1) has been reported. The framework adopts a dia topology (M-L-M angle is close to 156°). ZTF-1 shows high CO(2) (273 K) and H(2) (77 K) uptake due to the presence of the free -NH(2) group and uncoordinated tetrazolate nitrogen.
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Tamas Panda
Centre for Environment Education
Pradip Pachfule
S.N. Bose National Centre for Basic Sciences
Yifei Chen
University of Science and Technology of China
Chemical Communications
National University of Singapore
National Chemical Laboratory
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Panda et al. (Wed,) studied this question.
synapsesocial.com/papers/69dd4d1127c48be1bb40cb9f — DOI: https://doi.org/10.1039/c0cc04169f