Key points are not available for this paper at this time.
The air-stable phosphine sulfide (tBu)2P(S)H serves as a ligand precursor for the efficient nickel-catalyzed cross-coupling reactions of a variety of unactivated aryl chlorides with aryl Grignard reagents (Kumada−Tamao−Corriu reaction) at room temperature to yield the corresponding biaryls with isolated product yields ranging from 79 to 97%.
Li et al. (Fri,) studied this question.