September 9, 2021Open Access

Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization–Hydroboration of Unactivated Alkenes

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Abstract

)-H bonds aided by native directing groups is described herein. The method is characterized by its simplicity, exquisite regio- and chemoselectivity, and wide substrate scope, offering a complementary site-selectivity pattern to other metal-catalyzed borylation reactions and chain-walking protocols.

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Jankins et al. (Thu,) studied this question.

synapsesocial.com/papers/6a028d5467f6ea5cc87548b0 https://doi.org/https://doi.org/10.1021/jacs.1c07162

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