In this study, acid-treated lamellar perlite (ALP) and Fe3O4-decorated acid-treated lamellar perlite (Fe3O4-ALP) were synthesized and applied as sorbents for dispersive solid-phase extraction coupled with flame atomic absorption spectrometry (DSPE-FAAS) for trace Co(II) determination. The synthesized materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDX), and BET surface area analysis. Fe3O4 decoration onto the lamellar aluminosilicate framework of perlite yielded a mesoporous composite with enhanced surface heterogeneity and convenient magnetic recoverability, facilitating rapid phase separation in the DSPE workflow. Comparative experiments demonstrated that Fe3O4-ALP exhibited substantially higher extraction efficiency than ALP, confirming the beneficial role of Fe3O4 decoration on Co(II) uptake. Under optimized analytical conditions, the DSPE-FAAS method showed a linear response for Co(II) in the range of 5–250 ng mL–1 with a correlation coefficient exceeding 0.999. The limits of detection and quantification were determined as 0.626 ng mL–1 and 2.086 ng mL–1, respectively, corresponding to a 122-fold LOD improvement factor relative to direct FAAS analysis. The method exhibited satisfactory precision, with relative standard deviations ranging from 4.4% to 8.1%. The applicability of the developed DSPE-FAAS method was validated by analyzing groundwater and rock leachate samples, which yielded recoveries in the range of 84.4–110.4%, confirming method robustness under geochemically complex matrix conditions. Overall, Fe3O4-ALP represents a cost-effective and analytically efficient sorbent for trace Co(II) determination in environmental samples.
Ali Kılıçer (Thu,) studied this question.