Key points are not available for this paper at this time.
intermetallic shell on Pt nanoparticles. The turnover rates (TORs), propylene selectivity, and stability of these bimetallic catalysts significantly surpass those of the monometallic Pt catalyst for propane dehydrogenation. At the same time, TORs increase with increasing the Pt-Sn coordination number, whereas propylene selectivity is not significantly influenced by the Pt-Sn coordination number. Combined with experiments and theoretical calculations, the high propylene selectivity of Pt-Sn bimetallic nanoparticles is attributed to the geometric effects of Sn that reduce the Pt ensembles, and the high TORs are due to the electronic effects that weaken Pt-hydrocarbon chemisorption energies.
Ye et al. (Tue,) studied this question.