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Abstract The charge transport in blue light‐emitting polyspirobifluorene is investigated by both steady‐state current‐voltage measurements and transient electroluminescence. Both measurement techniques yield consistent results and show that the hole transport is space‐charge limited. The electron current is found to be governed by a high intrinsic mobility in combination with electron traps. Numerical simulations on light‐emitting diodes reveal a shift in the recombination zone from the cathode to the anode with increasing bias.
Nicolai et al. (Tue,) studied this question.