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Hybrid pigment colorants with intricate supramolecular architectures—have rapidly ascended as a pivotal class of multifunctional materials at the nexus of solid-state chemistry and advanced materials engineering. This review offers a critical synthesis of their structural foundations, chromogenic mechanisms, and functional versatility, highlighting state-of-the-art synthetic approaches and the role of host–guest interactions such as hydrogen bonding, π–π stacking, and coordination phenomena. Central to the discussion is the structure–properties relationship, elucidating how the geometry, surface chemistry, and porosity of inorganic hosts dictate optical properties, thermal and chemical stability, as well as functional performance. A detailed analysis of hybrid pigments embedded in polymer matrices, including thermoplastics, thermosets, and elastomers, is presented, with emphasis on their effects on mechanical reinforcement, UV resistance, barrier performance, flammability, hydrophobicity, pH responsiveness, and antimicrobial activity. By integrating concepts from pigment chemistry, interfacial science, and polymer physics, this review provides a framework for the rational design of next-generation functional colorants and connects fundamental design principles with application-oriented performance. The discussion critically covers the full life cycle of hybrid pigments, from synthesis and interfacial interactions to stability, multifunctional properties, and their integration into diverse high-performance polymer systems. • Comprehensive review of functional hybrid pigments for advanced polymer systems. • Structure–property relationships governing optical and multifunctional performance. • First unified analysis of hybrid pigments across thermoplastics, thermosets and elastomers. • Lifecycle-driven design rules for multifunctional colorants in polymer composites.
Szadkowski et al. (Sun,) studied this question.