Stable in Four Oxidation States: Exploring the Redox-Variability of Molybdenum and Tungsten Triazolylidene Complexes

Key Points

• This research investigates the stability of molybdenum and tungsten complexes across various oxidation states.
• Analytical techniques were used to assess ligand stability.
• Triazolylidene ligands were synthesized and tested for their stabilizing properties.
• Comparative assessments were made between different complexes.
• Molybdenum and tungsten complexes exhibit stability in four distinct oxidation states.
• MIC ligands effectively stabilize these complexes for use in catalysis.
• The findings indicate promising applications in small molecule activation.