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Radium and barium are hazardous contaminants that frequently occur in wastewater, posing significant risks to human health and the environment. This study provides a comparative evaluation of five synthetic zeolites—3A, 4A, 5A, 13X (commercial), and NaP1 (synthesized from fly ash)—representing three distinct framework types (LTA, FAU, and GIS) for the removal of radium from real saline mine water (Upper Silesia Coal Basin, Poland) and barium from synthetic water. The zeolites were characterized by XRD, SEM-EDS, and N2 adsorption, and tested in both granular and fine-powder forms using sequential batch adsorption experiments. For radium removal from mine water, zeolite NaP1 demonstrated superior performance, maintaining low 226Ra effluent activity (<1 Bq/L), even after treating ~50 L of water. Zeolites 3A, 4A, 5A, and 13X exhibited significantly lower performance than NaP1, showing poor selectivity for radium. In the barium batch tests, all tested zeolites achieved removal efficiencies exceeding 95% at low initial concentrations (100 mg/L). At higher concentrations (2000 mg/L), zeolites 3A, 4A, and 13X exhibited the highest adsorption capacities, with zeolite 4A achieving the maximum value of approximately 239.9 mg/g. The experiments demonstrated that idealized laboratory conditions can substantially overestimate sorbent performance relative to real water systems.
Samolej et al. (Tue,) studied this question.