Supramolecular Hydrogels and High‐Aspect‐Ratio Nanofibers through Charge‐Transfer‐Induced Alternate Coassembly

Gelling together: The alternate coassembly of a noncovalent donor–acceptor (D–A) amphiphilic pair in water results in very long nanofibers that form hydrogels (see scheme). Microscopic and single-crystal studies have provided an insight into the hierarchical self-assembly of the charge-transfer (CT) amphiphile, which consists of coronene and a viologen derivative, into cylindrical micelles and gels as the concentration of the D–A pair is increased. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.