Halogenated Materials as Organic Semiconductors

Organic semiconductors have great potential as the active material in low-cost, large area plastic electronics, whether as light-emitting diodes (LEDs), field-effect transistors (FETs) or solar cells. Organic semiconducting materials retain the processability associated with polymers while maintaining good optoelectronic properties, for example, high absorption coefficients for photons in the visible, and field-effect mobilities comparable with that of amorphous silicon. The elucidation of important structure−property relationships is vital for the design of functional, high-performance organic semiconductors. In this short review, we summarize such relationships stemming from the halogenation of organic semiconductors. While it has been known in the past decade that fluorination lowers the energy levels in carbon based systems, induces stability and electron transport, less is known about the effect of the other halogens. Chlorination has recently been shown to be a viable route to n-type materials. The bandgap of conjugated compounds can also be decreased slightly by the addition of Cl, Br, and I to the aromatic core. The effect of the halogenated moieties on the packing of molecules is discussed.