The study aims to explore the release mechanisms of HNO and NO from specific cobalt(II)-nitrosyl complexes.
Synthesis of Co-nitrosyl complex [Co(TMTAA 2-)(NO)]
Characterization of the complex using spectroscopic techniques
Assessment of ligand-induced release under controlled conditions
Successful release of HNO/NO was observed under specific conditions
Demonstrated unique behavior of cobalt(II)-nitrosyl complexes in different environments
Identified factors influencing the release mechanism
Abstract
The number of Co-nitrosyls having Co (NO) 8 configuration, which donate HNO under specific reaction conditions, is only a handful. A Co-nitrosyl complex, Co (TMTAA 2 ˉ) (NO), 1a [TMTAA 2 ˉ =. . .