Ligand induced release of HNO/NOˉ from a cobalt(II)-nitrosyl complex

Biplab Mondal; Bristi Maina Deka; Shankhadeep Saha; Ankur Kanti Guha

doi:10.1039/d6cc00661b

January 1, 2026Chemical Communications

Ligand induced release of HNO/NOˉ from a cobalt(II)-nitrosyl complex

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Key Points

The study aims to explore the release mechanisms of HNO and NO from specific cobalt(II)-nitrosyl complexes.
Synthesis of Co-nitrosyl complex [Co(TMTAA 2-)(NO)]
Characterization of the complex using spectroscopic techniques
Assessment of ligand-induced release under controlled conditions
Successful release of HNO/NO was observed under specific conditions
Demonstrated unique behavior of cobalt(II)-nitrosyl complexes in different environments
Identified factors influencing the release mechanism

Implication

This investigation demonstrates the release of HNO/NO from a cobalt-nitrosyl complex, suggesting new pathways for chemical reactions.

Abstract

The number of Co-nitrosyls having {Co(NO)} 8 configuration, which donate HNO under specific reaction conditions, is only a handful. A Co-nitrosyl complex, [Co(TMTAA 2 ˉ)(NO)], 1a [TMTAA 2 ˉ =...

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Cite This Study

Mondal et al. (2026) studied this question.

synapsesocial.com/papers/69cf5ecb5a333a821460d620 https://doi.org/10.1039/d6cc00661b

View Full Paper

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Ligand induced release of HNO/NOˉ from a cobalt(II)-nitrosyl complex

Key Points

Implication

Abstract

Discussion

Cite This Study

Ligand induced release of HNO/NOˉ from a cobalt(II)-nitrosyl complex

Key Points

Implication

Abstract

Discussion

Cite This Study

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