Key points are not available for this paper at this time.
A porous metal-organic framework, Co(II)(4)(micro-OH(2))(4)(MTB)(2) x (H(2)O)(4)(n) x 13nDMF x 11nH(2)O (SNU-15), has been prepared; the X-ray crystal structure reveals a CaF(2)-like structure that generates 3D channels and the desolvated solid Co(II)(4) (micro-OH(2))(4)(MTB)(2)(n) (SNU-15') exhibits selective gas sorption properties for H(2) and O(2) gases over N(2) at 77 K, with exceptionally high O(2) density, as well as for CO(2) over CH(4) at 195 and 273 K, suggesting its potential application in gas separation processes.
Cheon et al. (Thu,) studied this question.