A porous metal-organic framework, [Co(II)(4)(micro-OH(2))(4)(MTB)(2) x (H(2)O)(4)](n) x 13nDMF x 11nH(2)O (SNU-15), has been prepared; the X-ray crystal structure reveals a CaF(2)-like structure that generates 3D channels and the desolvated solid [Co(II)(4) (micro-OH(2))(4)(MTB)(2)](n) (SNU-15') exhibits selective gas sorption properties for H(2) and O(2) gases over N(2) at 77 K, with exceptionally high O(2) density, as well as for CO(2) over CH(4) at 195 and 273 K, suggesting its potential application in gas separation processes.
No takes yet. Share an insight, caveat, or question.
Cheon et al. (2009) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:
More from Chemical Communications