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November 4, 2012Angewandte Chemie International Edition298 citations

Visible‐Light‐Induced Photocatalytic Reductive Transformations of Organohalides

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HKHyejin KimUniversity of Science and TechnologyCLChulbom LeeSeoul National University

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Abstract

A photo opportunity: A visible-light-excited iridium catalyst delivers electrons from an amine to an organohalide. The electron transfer then induces reductive scission of the carbon–halogen bond, generating the corresponding alkyl, alkenyl, and aryl radical that can undergo cyclization and hydrodehalogenation reactions.

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Cite This Study

Kim et al. (2012) studied this question.

synapsesocial.com/papers/6a6a23d31a81d9d79648578ahttps://doi.org/10.1002/anie.201203599
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