Abstract The imperative to minimize iridium usage in proton exchange membrane water electrolysis (PEMWE) process presents a pivotal challenge for hydrogen economy deployment, while inherent destabilization of iridium (Ir) active sites under corrosive operational conditions, originating from insufficient Ir bonding strength, remains a fundamental barrier. Here, we resolve this dilemma through heterointerface‐engineered stabilization, where the strategically constructed Nb‐TiO 2 rutile/anatase heterophase homojunction stabilizes Ir sites with enhanced orbital overlap and intensified charge transfer. This atomic‐scale anchoring mechanism, validated by operando characterization and theoretical calculations, strengthens Ir─O support bonding and optimizes *OOH adsorption energetics, thereby enabling concurrent activity‐stability improvements. The resultant Ir@IrO x /m‐Nb‐TiO 2 anode achieves exceptional PEMWE performance with ultralow loading (0.27 mg Ir cm −2 ), requiring a low electrolysis voltage of 1.72 V to reach industrial current densities of 2 A cm −2 , coupled with unprecedented durability with <1.7% voltage decay over 3000 h. This interface design philosophy establishes a general paradigm for developing active and stable supported electrocatalysts for PEMWE and beyond.
Ni et al. (Fri,) studied this question.
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