Raising Near-Infrared Photoluminescence Quantum Yield of Au42 Quantum Rod to 50% in Solutions and 75% in Films

Highly emissive gold nanoclusters (NCs) in the near-infrared (NIR) region are of wide interest, but challenges arise from the excessive nonradiative dissipation. Here, we demonstrate an effective suppression of the motions of surface motifs on the Au