Preparation of Self-healing Thermoplastic Polysiloxane–Polyurea/Polyether–Polyurea Elastomer Blends with a Co-continuous Microphase Structure and In-Depth Research on Their Synergistic Effects

Polymer blending has been an important method to create materials with specific properties that have synergistic effects. However, there are few reports on the mechanism of synergistic effects. It is well known that it is quite difficult to obtain ideal blends composed of nonpolar organosilicon polymers and polar polymers. In this paper, thermoplastic polyurea elastomer blends with a co-continuous microphase structure consisting of polysiloxane-polyurea (PDMS-PUA), polyether amine-polyurea (PEA-PUA), and compatibilizer PDMS-PUA-grafted PEA-PUA (PDMS-PUA-g