Silicon Solid State Battery: The Solid‐State Compatibility, Particle Size, and Carbon Compositing for High Energy Density

Abstract Solid‐state battery research has gained significant attention due to their inherent safety and high energy density. Silicon anodes have been promoted for their advantageous characteristics, including high volumetric capacity, low lithiation potential, high theoretical and specific gravimetric capacity, and the absence of lethal dendritic growth. Addressing concerns such as low conductivity, pulverization, fracture, dense solid electrolyte interface layer, and low coulombic efficiency has substantially improved the use of silicon electrodes in solid‐state batteries. Researchers have explored carbon additions, solid electrolyte suitability for Si anodes, pressure optimization, and particle size effects (nano/micro) to enhance energy density. Recent studies have investigated the conductivity mechanism, stack pressure, and anode‐solid electrolyte compatibility to improve energy density. Micro‐ and nano‐sized silicon have attracted attention in carbon‐based composites due to their exceptional conductivity, uniform distribution, efficient electron migration, and diffusion channels. The development of solid‐state batteries with high energy density, safety, and extended lifespan has been a major focus. This review sheds light on significant insights and strategic approaches for researchers working on solid‐state silicon‐based systems to overcome existing challenges.