Nomenclature of the ancylite supergroup

Abstract The ancylite supergroup has been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association, with the general crystal chemical formula ( M 3+ x M 2+ 2– x )(CO 3 ) 2 (OH) x ⋅(2– x )H 2 O (1 ≤ x ≤ 2, Z = 2). The ancylite supergroup can be divided into two groups defined by different proportions of the M cation and hydroxyl anion and/or water molecule: the ancylite group is defined for 1 ≤ x ≤ 1.5; the kozoite group is defined for 1.5 < x ≤ 2. The ancylite supergroup minerals are orthorhombic with space group Pmcn , or monoclinic with space group Pm 11, and have a crystal structure with species-defining trivalent and divalent M cations ( M = La 3+ , Ce 3+ , Nd 3+ , Ca 2+ , Sr 2+ and Pb 2+ ) which centre ten-vertex polyhedra formed by oxygen atoms at three independent O sites. Two vertices of the triangular (CO 3 ) 2– anion are oxygen atoms, whereas the third one, O(3), is statistically filled with (OH) – groups and H 2 O molecules. The triangular faces of three oxygen atoms of M O 10 coordination polyhedra join the chains of this ten-vertex polyhedron, which is extended along the c axis. The (CO 3 ) triangles connect chains in three dimensions. To date, eight valid mineral species with M 2+ = Sr 2+ , Ca 2+ and Pb 2+ belong to the ancylite group ancylite-(La), ancylite-(Ce), calcioancylite-(La), calcioancylite-(Ce), calcioancylite-(Nd), gysinite-(La), gysinite-(Ce) and gysinite-(Nd). Two hydroxyl carbonates with only rare earth elements as species-defining cations, kozoite-(La) and kozoite-(Nd) are members of the kozoite group.