Abstract. To what extent the new particle formation (NPF) contributed to the cloud condensation nuclei (CCN) remained unclear, especially at the boundary layer top (BLT) in polluted atmosphere. Based on measurements at a mountain-top background site in southeastern China during spring 2024, this study systematically investigates the nucleation mechanism and subsequent growth dynamics of NPF events under contrasting air masses, and quantifies their role as a source of CCN. Eight NPF events were observed, and three of them occurred in the polluted conditions (NPF-P) which associated with regional transportation while the rest five events appeared in the clean conditions (NPF-C). The average formation rate (J2. 5: 2. 4 cm-3s-1 vs. 0. 7 cm-3s-1) and growth rate (GR: 6. 8 nm h−1 vs. 5. 5 nm h−1) were significantly higher in NPF-P events than in NPF-C events, alongside elevated concentrations of sulfuric acid and ammonia. The correlation between log J3 and H2SO4, as well as theoretical simulations with the MALTEBOX model, indicates that the enhanced nucleation in polluted conditions can be attributed to the participation of ammonia in stabilizing sulfuric acid-based clusters. In addition, much higher CCN enhancement factor was observed in NPF-P (EFCCN: 1. 6 vs. 0. 7 in NPF-C) due to the regional transported of anthropogenic pollutants from the urban cluster regions and their secondary transformation under enhanced atmospheric oxidation capacity. Furthermore, the duration of NPF-to-CCN conversion was quantified using a “Time Window (τ) ”, revealing that polluted conditions accelerated the conversion by 17. 0 % (τ = 16. 4 h vs. 19. 8 h). Nitrate played an important role in maintaining a rapid particle growth rate, thereby shortening τ and enhancing CCN production from NPF – a process that can ultimately influence cloud microphysical properties by increasing the potential cloud droplet number concentration. These findings reveal that polluted air masses enhance both the efficiency and speed of CCN production at the BLT through elevated atmospheric oxidation capacity.
Zhu et al. (Fri,) studied this question.