Nanocluster-stabilized sulfur-based superradical is reported by Zhikun Wu and co-workers in the Research Article (e17738). The superradical Au64(CPT)31S· was obtained through the homolytic cleavage of the thiolate S─C bond in the Au64(CPT)32 nanocluster precursor by radiative or solvent-induced methods. It can initiate the polymerization of pentaerythritol triacrylate in 3D printing despite its ultrastability. In addition, the superradical and its precursor exhibit NIR-II photoluminescence and high photothermal conversion efficiencies.
Hu et al. (Thu,) studied this question.
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