The electrochemical interaction between aggressive ions and metals plays a key role in corrosion failure processes. The Langmuir adsorption isotherm equation was employed to reveal that surface coverage remains largely unchanged at higher concentrations, with the concentration effect partially mediated by the dielectric properties of the solution. The work function and adsorption energy of two typical corrosive elements, Cl and S, adsorbed on the surfaces of two metals (Al and Cu) were systematically calculated. By adjusting solubilization parameters in different implicit solvent models, variations in dielectric properties at similar surface coverage under different concentrations were simulated. It was observed that as the solution concentration increased, the electrostatic shielding effect of the surface solution was enhanced, while the changes in adsorption energy were not statistically significant. However, the work function was found to increase by approximately 20–90 meV with increasing concentration, with the magnitude of this increase dependent on the metal type and surface orientation. This enhancement further strengthened the adsorbate–substrate interaction, thereby influencing the electrochemical reaction kinetics of the surface material.
Lv et al. (Mon,) studied this question.