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Post-synthesis thermal annealing of ZIF-8 close to its framework decomposition temperature below 550 °C results in a modified structure with highly enhanced and stable cyclic CO2 adsorption capacity of over 1.5 mmol g−1 at 25 °C and 1 bar of CO2, which is over 100% greater than that of initial ZIF-8.
Gadipelli et al. (Wed,) studied this question.