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Hip to be square: Styrenes participate in 2+2 cycloadditions upon irradiation with visible light in the presence of an iridium(III) polypyridyl complex. In contrast to previous reports of visible light photoredox catalysis, the mechanism of this process involves photosensitization by energy transfer and not electron transfer.
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Lu et al. (Mon,) studied this question.
synapsesocial.com/papers/69d75acbef4aa71f97f30d6b — DOI: https://doi.org/10.1002/anie.201204835
Zhan Lu
State Key Laboratory of Pollution Control and Resource Reuse
Tehshik P. Yoon
University of Wisconsin–Madison
Angewandte Chemie International Edition
University of Wisconsin–Madison
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