Solventless reaction dramatically accelerates supramolecular self-assemblyElectronic supplementary information (ESI) available: experimental details and CD spectra. See http://www.rsc.org/suppdata/cc/b2/b203651g/

It has been disclosed that the supramolecular self-assembly is dramatically accelerated under solvent-free conditions leading to higher-order fabrications of two- or three-dimensional topology and even double helicates.