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Abstract Expedient CH aminocarbonylations of unactivated (hetero)arenes and alkenes were accomplished with a cobalt(III) catalyst that shows high functional group tolerance. The CH functionalization occurred with excellent chemo‐, site‐, and diastereoselectivity and enabled step‐economical reactions with isocyanates or acyl azides.
Li et al. (Tue,) studied this question.
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