August 11, 2005

Origin of the High Activity of Second‐Generation Grubbs Catalysts

Puntos clave

Los puntos clave no están disponibles para este artículo en este momento.

Resumen

Green light for alkene metathesis: A strong σ-donor ligand L favors the active conformation (green in the scheme) of the carbene ligand in the ruthenium complex and thus leads to high catalytic activity of the second-generation Grubbs catalysts.

Preguntar a la IA

Me gusta

Guardar

Cite This Study

Bernd F. Straub (Thu,) studied this question.

synapsesocial.com/papers/69dbde5d7d378569a98367dc https://doi.org/https://doi.org/10.1002/anie.200501114

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques1971 · 1,061 citations
2Die Rotation des Liganden unterscheidet die Ruthenium-Metathesekatalysatoren der ersten und zweiten Generation2002 · 25 citations
3Highly Active Ruthenium Catalysts for Olefin Metathesis: The Synergy of N‐Heterocyclic Carbenes and Coordinatively Labile Ligands1999 · 494 citations
4Ligand Rotation Distinguishes First- and Second-Generation Ruthenium Metathesis Catalysts2002 · 122 citations
5Density-functional thermochemistry. III. The role of exact exchange1993 · 102,936 citations

Preguntar a la IA

Me gusta

Guardar