January 1, 2024

Unusual linkage photoisomerization in Co(NH3)2NO22I3Cl single crystals

PKPolina P. KalininaNovosibirsk State University BZB.A. ZakharovNovosibirsk State University

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Resumen

The reaction Co(NH 3 ) 5 NO 2 2+ → Co(NH 3 ) 5 ONO 2+ proceeds under visible light for cations in certain crystallographic positions only in Co(NH 3 ) 5 NO 2 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure.

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Cite This Study

Kalinina et al. (Mon,) studied this question.

synapsesocial.com/papers/69decba35e217d93a5558968 https://doi.org/https://doi.org/10.1039/d4ce00734d

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2Distortion of Crystal Structures of Some CoIII Ammine Complexes. I. Distortion of Crystal Structure of [Co(NH3)5NO2]Cl(NO3) on Cooling1997 · 36 citations
3Crystal space analysis by means of Voronoi–Dirichlet polyhedra1995 · 152 citations
4Reactivity of molecular solids1999 · 137 citations
5Distortion of Crystal Structures of Some CoIII Ammine Complexes. III. Distortion of Crystal Structure of [Co(NH3)5NO2]Cl2 at Hydrostatic Pressures up to 3.5 GPa1998 · 54 citations

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