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November 5, 1968Physical Review214 citations

Atomic Bethe-Goldstone Equations. III. Correlation Energies of Ground States of Be, B, C, N, O, F, and Ne

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RNR. K. Nesbet

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Abstract

A variational formulation of Brueckner's theory has been used to solve Bethe-Goldstone equations and to compute electronic pair-correlation energies for the atoms listed in the title. One-electron effective correlation energies, needed for open-shell atomic states, are also computed. An approximate Hartree-Fock function is used for the reference state in each case. Individual pair-correlation energies are computed to an expected accuracy of 0. 001 Hartree a. u. The total correlation energies range from 98. 5 to 100. 3% of the empirical correlation energy. For comparison with many-particle perturbation theory, definitions of the hierarchy of nth-order Bethe-Goldstone equations and of the concepts of gross and net mean-value increments used in this work are restated in terms of linked Goldstone diagrams.

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R. K. Nesbet (1968) studied this question.

synapsesocial.com/papers/69fc05506d730ca589dd6f94https://doi.org/10.1103/physrev.175.2
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