Highly Emissive Organic Single‐Molecule White Emitters by Engineering o‐Carborane‐Based Luminophores

The development of organic single-molecule solid-state white emitters holds a great promise for advanced lighting and display applications. Highly emissive single-molecule white emitters were achieved by the design and synthesis of a series of o-carborane-based luminophores. These luminophores are able to induce multiple emissions to directly emit high-purity white light in solid state. By tuning both molecular and aggregate structures, a significantly improved white-light efficiency has been realized (absolute quantum yield 67 %), which is the highest value among the known organic single-molecule white emitters in the solid state. The fine-tuning of the packing modes from H- to J- and cross-stacking aggregates as well as intermolecular hydrogen bonds are successful in one molecular skeleton. These are crucial for highly emissive white-light emission in the solid state.