February 19, 2020

Rhodium‐Catalyzed ortho‐Olefination of Sterically Demanding Benzamides: Application to the Asymmetric Synthesis of Axially Chiral Benzamides

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Resumen

-catalyzed diastereoselective ortho C-H bond olefination enabled the asymmetric synthesis of axially chiral N,N-dialkylbenzamide derivatives with high ee values.

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Yoshimura et al. (Wed,) studied this question.

synapsesocial.com/papers/6a01d41b60baf37e2cd8bd12 https://doi.org/https://doi.org/10.1002/chem.202000797