February 27, 2018

Low‐Coordinate Single‐Ion Magnets by Intercalation of Lanthanides into a Phenol Matrix

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; Ln=Tb, Dy, Ho, Er, Tm). These complexes and the free ligand ArOH were isostructural. Magnetic measurements and theoretical studies demonstrated that both the oblate-type dysprosium and prolate-type erbium analogues exhibited single-ion magnet (SIM) behavior. The bulky phenol ligands provided strong uniaxial ligand field, making the dysprosium SIM possessing blocking barrier up to 961 K.

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Meng et al. (Tue,) studied this question.

synapsesocial.com/papers/6a01edfb0cec8eebbd5cb5d8 https://doi.org/https://doi.org/10.1002/anie.201801223

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