Fulvalene-Bridged Binuclear Complexes: Strongly Antiferromagnetically Coupled Ru III Ru III and Class II–III Mixed-Valence Ru III Ru II
Puntos clave
This research aims to investigate the antiferromagnetic coupling in fulvalene-bridged binuclear complexes of ruthenium.
Theoretical calculations were performed to analyze magnetic interactions.
EPR spectroscopic techniques were used to evaluate electronic properties.
EPR signals were absent, confirming diamagnetic behavior.
The theoretical calculations supported the presence of antiferromagnetic coupling.
Resumen
-based unpaired electrons.This assignment is confirmed by the absence of EPR signals and the diamagnetic behavior and is further supported by theoretical calculations.