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An asymmetric allylic substitution-isomerization reaction utilizing hydrogen-bonding assisted central-to-axial chirality transfer successfully produces configurationally stable axially chiral enamides with high yields and enantioselectivities. Novelty: ClaimNovelty.METHODOLOGICAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

Asymmetric allylic substitution–isomerization to axially chiral enamides via hydrogen-bonding assisted central-to-axial chirality transfer

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