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Recombination and Disproportionation Reactions of Iodine Atoms and Ethyl Radicals | Synapse

January 1, 1963

Recombination and Disproportionation Reactions of Iodine Atoms and Ethyl Radicals

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Resumen

In order to obtain information regarding disproportionation and recombination reactions of ethyl radicals and iodine atoms we have investigated the photolysis of various mixtures of diethyl ketone and methyl iodide. Ethyl radicals, produced by photolysis of diethyl ketone, react with iodine atoms, produced by photolysis of methyl iodide, according to reactions (13) and (14) C2H5+I→C2H4+HI,C2H5+I→C2H5I.The results indicate k13/k14=0.33±0.03. The influence of added gas and the effect of temperature are discussed.

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Cite This Study

Guercione et al. (Tue,) studied this question.

synapsesocial.com/papers/6a088e86ad370a6b44de2e4c https://doi.org/https://doi.org/10.1063/1.1733446