March 1, 2002

HeterotriangulenesStructure and Properties

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Resumen

We report the solid-state structure, electrochemical properties, and photochemical properties of 1 and 2. The single-crystal X-ray structure shows that 1 assembles into densely packed columnar π-stacks. 2 is observed as a racemic mixture of atropisomers in the solid state. The oxidation potential of 2 is similar to that of triphenylamine (∼1 V). Both 1 and 2 show strong fluorescence at 422 and 458 nm, respectively.

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Field et al. (Fri,) studied this question.

synapsesocial.com/papers/6a08cf1027ceb0c2a2d5fadf https://doi.org/https://doi.org/10.1021/cm010929y

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