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We show that the gradient expansion of the Kohn-Sham potential does not exist for the case of pure exchange but that when correlation is taken into account by screening the exchange, the expansion does exist and has a different dependence on the charge density than that assumed by Herman et al. and by Sham. We obtain the gradient term to all powers in e^2. Our gradient term vanishes in regions where the charge density vanishes, unlike the gradient term calculated by Herman et al. and Sham which becomes infinite.
Leonard Kleinman (Sun,) studied this question.