Rapid stress‐induced crystallization in natural rubber

Abstract Stress‐induced crystallization in a rapidly stretched natural rubber gum vulcanizate has been studied using thermal techniques to follow the development of crystallinity. A special‐purpose analog computer has been assembled and used on‐line to process the thermal and mechanical data obtained in high speed tensile testing. Roughly first‐order room temperature crystallization kinetics curves were obtained having time constants of 50–60 msec in the range of 400–540% extension. While the rate of this rapid, presumably primary crystallization appears rather insensitive to elongation in this limited range, the extent of crystallization at 400 msec increases smoothly from zero at 340% elongation to around 18% at 540% elongation. It is shown that our high‐speed tensile tester can stretch this vulcanizate fast enough that most of the crystallization takes place after extension has been completed. Stress‐strain curves obtained at this high rate are compared with those obtained at lower rates where crystallization takes place during the stretching.